Romania is a great place to shop! chaep and quality! scotland isn't bad but you have to shell out a few hundered K for the players...
a few randomers are Mika Aaritalo (i think thats the spelling) for 24k or there about, Mauro zarate for 3Mil, plays for anyteam (in my Man Utd game, he kicked rooney off firt team duties!)
Romanian team Poli 1921 have good players, and most belgium 2nd division teams slot into league one teams straight away for cheap (Kirk Hilton, 26, DL, 24k, Antwerp)
if you have arg and brazil on full detail, most clubs there have premiership quality players...
Lebohang Mokoena is good, but sometimes work permit is a pain...
Orlando pirates, and other south african and zimbabue teams have some good
hope that helps...