Quality Printing
First question is: did you calibrate your monitor? If so, when in RGB mode, create a greyscale ramp with four hues: draw a rectangular selection, and fill it with black (0,0,0) the next one with dark grey (64,64,64), another one with medium grey (128,128,128) and a last one with light grey (192,192,192). Print this on the paper you use for the photographs (I do hope you use photo quality paper!), let dry then scan it again. Uuse the measure tool set to a few pixels and look at what those printed values do in Photoshop. Also measure the white" of the paper this way. The measured values "should" be identical. If they aren't, adjust your printer soft untill it matches and save this as your setting for this paper.
Do keep in mind that a monitor will always look brighter as it displays light colours, while print has to do with only reflected light. Also, four inks just cannot match what RGB has to offer.
One last remark: except when your printer software explicitely says it needs sRGB, use AbobeRGB, Matches print much better.
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