Maracana Stadium seats about 95000 I think. The biggest in the world is Rungrado May Day stadium in North Korea with a capacity of 150,000. Its not a dedicated football stadium though (I think). Salt Lake stadium in Calcutta, India, is huge as well with a 120,000 capacity. Although its also a multi-use stadium, its mainly used for football matches. It hosts the home games for Mohammedan SC, East Bengal and Mohun Bagan (they are 3 of the biggest football clubs in India). I've been there, its bloody massive!
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